Preview

SIBERIAN JOURNAL OF PHYSICS

Advanced search

Temperature Dependence of the Specific Heat Capacity Glasses Produced Based on Na2B4O7 + Bi2O3

https://doi.org/10.25205/2541-9447-2023-18-3-61-70

Abstract

In this work, the temperature dependence of the specific heat capacity of glasses obtained on the basis of the Na2B4O7 + Bi2O3 compound with different concentrations of sodium tetraborate and bismuth oxide in the initial mixture was studied experimentally during cooling. It has been experimentally shown that with a change in the concentration of the initial substances, the specific heat capacity of the sample’s changes, and a shift of the maxima towards low temperatures is observed with an increase in the concentration of bismuth oxide. A physical interpretation of the nature of the maximum on the temperature dependence of the specific heat is given.

About the Authors

D. S. Kuchakshoev
S. U. Umarov Physical-Technical Institute of the National Academy of Sciences of Tajikistan
Tajikistan

Davlatnazar S. Kuchakshoev, Senior Researcher

Dushanbe



А. G. Dzhaborov
S. U. Umarov Physical-Technical Institute of the National Academy of Sciences of Tajikistan
Russian Federation

Alexander G. Dzhabаrov, Candidate of Physical and Mathematical Sciences

Dushanbe



А. Kholov
S. U. Umarov Physical-Technical Institute of the National Academy of Sciences of Tajikistan
Russian Federation

Alimakhmad Kholov, Candidate of Chemical Sciences

Dushanbe



References

1. Guloyan Yu. A. Technology of glass and glass products: a textbook for secondary specialized educational institutions, systems of vocational and industrial training. Vladimir, Transit-X, 2003, 480 p. (in Russ.)

2. Hasu H., Ito T., Hase H., et al. Third-Order Optical NonLinearity of Bi2O3–Based Glasses // J. Non-Cryst. Solids. 1996. Vol. 204, no. 1. P. 78–82.

3. Becker P. Thermal and Optical Properties of Glasses of the System Bi2O3–B2O3 // Cryst. Res. Technol. 2003. Vol. 38, no. 1. P. 74–82.

4. Ehrt D. The Effect of ZnO, La2O3, PbO and Bi2O3 on the Properties of Binary Borate Glasses and Melts // Phys. Chem. Glasses. 2006. Vol. 47, no. 6. P. 669–674.

5. Mazurin O. V., Strelytsina M. V., Shvaiko-Shvaykovskaya T. P. Properties of glasses and glass-forming melts: a Handbook. St. Petersburg, Nauka, 1998, vol. 6, part 2, 523 p.

6. Kuchakshoev D. S., Dzhabarov A. G. Differential thermal analysis of the binary system Bi2O3 + Na2B4O7 // DAN RT. 2015. Vol. 58, no. 12. P. 1096–1099.

7. Kargin Yu. F., Egorysheva A. V. Phase relationships in the Na2O-Bi2O3-B2O3 system // ZhNKh. 2005. Vol. 50, no. 12. P. 2068–2071.

8. Kuchakshoev D. S., Dzhabarov A. G., Kholov A. Properties of glasses based on Bi2O3 and Na2B4O7 compounds // DAN RT. 2020. Vol. 63, no. 7–8. P. 488–493.

9. Kuchakshoev D. S., Dzhabarov A. G., Kholov A. Determination of the specific heat capacity of glasses based on bismuth borates // Izvestiya NANT. Department of Physical and Mathematical, Chemical, Geological and Technical Sciences. 2022. No. 4 (189). P. 77–83.

10. Zinoviev V. E. Thermophysical properties of metals at high temperatures. Reference edition, Moscow, Metallurgiya, 1989, 384 p.

11. Bartenev G. M., Sanditov D. S. Relaxation processes in glassy systems. Novosibirsk, Nauka, 1986, 240 p.

12. Kuchakshoev D., Dzhabarov A. G., Kholov A. Computerized setup for studying the spectral characteristics of inorganic and organic materials based on GUR-5 and MDR-23. Collection of materials XV Numanov’s readings «The current state of chemical science and the use of its achievements in the national economy of the Republic of Tajikistan.» October 24, 2019, p. 81–83.

13. Kuchakshoev D., Dzhabarov A. G., Kholov A. Synthesis and optical properties of glasses based on Bi2O3-Na2B4O7 // Material scientific-practical conference on the topic «Problems of modern semiconductor physics». Kulyab, December 21, 2019, p. 34–37.

14. Sanditov D. S., Bartenev G. M. Physical properties of disordered structures. Novosibirsk, Nauka, 1982, 258 p.

15. Irtyugo L. A., Denisov V. M., Zhereb V. P., et al. High-Temperature Heat Capacity of Bismuth Borate Glasses // Zh. SFU. Chemistry. 2011. Vol. 4, no. 4. Р. 344–349.


Review

For citations:


Kuchakshoev D.S., Dzhaborov А.G., Kholov А. Temperature Dependence of the Specific Heat Capacity Glasses Produced Based on Na2B4O7 + Bi2O3. SIBERIAN JOURNAL OF PHYSICS. 2023;18(3):61-70. (In Russ.) https://doi.org/10.25205/2541-9447-2023-18-3-61-70

Views: 145


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2541-9447 (Print)